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Yttrium-Stabilized Zirconia: A Mouthful at Mach Speed

(Image source: ceramics.org)
A paper published as an "Early View" article by the Journal of the American Society shows that yttrium-stablized zirconia can be sintered to full density in a matter of seconds at 850 degrees Celsius. The key is subjecting the process to a dc electrical field above the critical threshold. Traditional YSZ sintering would require hours at 1450 degrees Celsius. The paper was written by Marco Cologna, Rishi Raj and Boriana Rashkova, who are in the process of testing other materials that they hope to be able to report on to the ceramic manufacturing community soon. An article from ceramics.org covers the story. Here's an excerpt:
"The trio's technique was fairly straightforward. They made dog-biscuit shaped samples from 3 mol% nanograin YSZ. They then sintered samples in a vertical tubular furnace, applying a constant dc voltage, varying temperature and voltage. In the stages of their tests, they encountered a phenomenon I have written about before: accelerated sintering speeds at lower temperatures, dubbed field-assisted sintering or "FAST". In fact Raj, Di Yang and Hans Conrad had recently published another paper about how low (20 V/cm) dc electric dields could speed sintering and slow grain growth."
With many radical advances taking place in the field of ceramics engineering since the end of the century, it should come as no surprise that a leap-forward in sintering technology is nigh on the horizon. While the process has not been perfected yet, and the reports are only preliminary at this point, those in our industry would do well to look forward to a more detailed report coming from this team in the coming months.
To learn more about ceramics engineering, check out Refractron:
To read the article from ceramics.org, following this link:
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New Stipulations From The EPA On The Horizon...

The latest article from Chemical and Engineering News discusses a new proposal by the Environmental Protection Agency, which states that chemical manufacturers may have to provide reports regarding processing, productions and purpose for using their compounds every four years instead of five. Under the Toxic Substances Control Act, chemical makers must report twice yearly to the EPA in order to keep the TSCA Inventory updated. This has been the standard ever since the presidency of George W. Bush, when the EPA changed its time frame to the now recognized five year policy (Previously it was four years also). The article states:
“The proposed rule “will allow the agency to more effectively and expeditiously identify and address potential chemical risks and improve the information available to the public on chemicals most commonly used in commerce,” says Steve Owens, EPA assistant administrator for the Office of Chemical Safety & Pollution Prevention. The agency expects to finalize the changes by mid-2011.”
In addition to these new stipulations, this proposal would also require that companies that engineer chemicals make known in advance that the data that is supplied to the EPA is confidential business information, or it could potentially be placed in the public domain. This is likely the result of the EPA administrator, Lisa P. Jackson’s recent campaign to stop unnecessary trade secret claims from some members of the chemical industry. What this means for chemical manufacturers is that it looks like it’s back to the old way of doing things, so be prepared to modify your budgets.
To read the article from Chemical and Engineering News, click here:
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New Zirconia Crowns May Replace The Metal Standard in Dentistry...
The study showed that after the mean survival time for posterior crowns (52 months), the probability for a PFZ crown to remain intact was 98.1%, where as the survival rate was only 95.8% for PFM crowns. This may not seem like a major difference, but ceramics manufacturers who specialize in Zirconia might see a boon to their businesses in the coming years as the Dental industry decides whether or not it will migrate to this new technology or stay with the PFM crowns that have served the profession for years.
The 22 practitioners were able to replicate these findings in different environments across three continents, and the results were the same regardless of oral location, whether molar or premolar. A total of 2,635 premolar and molar crowns were tested, and with the exception of the 1.9% of the PFZ crowns that failed, the results were almost unanimous: While the difference in the survival rate seems negligible, porcelain-fused-to-Zirconia crowns were superior to porcelain-fused-to-metal crowns. As medical technology continues to evolve, the demand for high-durability ceramics will continue to grow. Opportunities for expansion are on the horizon.
